Thermodynamics Gases and Temperature

Chemistry assignment help: Thermodynamics Gases and Temperature

1- A radio station’s channel, such as 100.7 FM or 92.3 FM, is actually its frequency in megahertz (MHz), where 1MHz=10 6 Hz and 1Hz=1s −1. Calculate the broadcast wavelength of the radio station 94.30 FM.

2- Hospital X-ray generators emit X-rays with wavelength of about 15.0 nanometers (nm), where 1nm=10 −9 m. What is the energy of the X-rays?

3- What is the azimuthal quantum number (also called the angular-momentum quantum number), ℓ, for the orbital shown here? Express your answer numerically as an integer.

4- What is the change in energy, ΔE , in kilojoules per mole of hydrogen atoms for an electron transition from n=3 to n=2

5- Here are some data collected on a sample of cesium exposed to various energies of light.
Light energy
Electron emitted? ElectronKE

3.87 no —
3.88 no —
3.89 yes 0
3.90 yes 0.01
3.91 yes 0.02

What is the threshold frequency ν 0 of cesium? Note that 1 eV (electron volt) =1.60×10 −19 J. Answer in Hz

6- The energy difference between two energy shells is calculated using the formula
ΔE=E f −E i where E f is the energy of the final shell, and E i is the energy of the initial shell from which the transition occurs. For example, for the transition n=4 to n=1 , the initial shell is the fourth shell, and the final shell is the first shell. Thus, the change in energy between the fourth and the first shell is denoted as ΔE=E 1 −E 4 . The energy corresponding to a shell is calculated using E n =−2.179×10 −18 /(n) 2 J
where n is the shell number. Calculate the energy difference for a transition in the Paschen series for a transition from the higher energy shell n=4. Express your answer to four significant figures and include the appropriate units.

7- A gas at 32 ºC occupies a volume of 250 mL. To what temperature must the gas be changed to occupy a volume of 285 mL?

8- An unknown gas effuses through a porous barrier at a rate that is 0.752 times the rate of Ar (g) under the same conditions. Which of the following is the unknown gas?

9- What is the density (g/L) of propane (C3H8) at STP (1 atm, 273 K)?

10- A system gives off 500 kJ of heat and does 100 kJ of work. What is the change in internal energy?

11- The heat of formation (ΔH°f) of MgCO3 (s) is -1095.8 kJ/mol. The chemical equation associated with this reaction is:

12- Consider:

2 B5H9 (g) + 12 O2 (g) → 5 B2O3 (g) + 9 H2O (g) ΔH˚reaction= – 8687 kJ.

What is the enthalpy change when 0.2500 moles of B5H9 are combusted?

13- Which of the following sets of quantum numbers is valid?

n = 1, l = 2, ml = 3, ms = 4

n = 3, l = 2, ml = -2, ms = 1/2

n = 1, l = 0, ml = 1, ms = -1/2

n = 4, l = 4, ml = -1, ms = 1/2

n = 0, l = 1, ml = 0, ms = -1/2
14- Consider the Bohr Model for the hydrogen atom. Which of the following electron transitions releases the MOST energy?

n = 6 to n = 4

n = 5 to n = 3

n = 4 to n = 2

n = 3 to n = 1

n = 2 to n = 1
15- The energy of one mole of photons having a wavelength of 630 nm is:
16- Use the data below to answer the questions.
Substance ΔH ∘ f (kJ/mol)

CF 4 (g)
− 679.9

CH 4 (g)
− 74.8

− 268.61

Keep in mind that the enthalpy of formation of an element in its standard state is zero.
Part A
Calculate the enthalpy change, ΔH ∘ , for the “expansion” of methane:CH 4 (g)→C(g)+4H(g)
Express your answer to one decimal place and include the appropriate units.
Part B
Calculate the enthalpy change, ΔH ∘ , for the reverse of the formation of methane: CH 4 (g)→C(s)+2H 2 (g) Express your answer to one decimal place and include the appropriate units.

17- The following table lists some enthalpy of formation values for selected substances.
Substance ΔH f ∘ (kJ/mol)


Al (OH) 3 (s)

H 2 O(l)

AlCl 3 (s)

H 2 O(g)

Part A
Determine the enthalpy for this reaction: AL(OH) 3 (s)+3HCl(g)→AlCl 3 (s)+3H 2 O(l)
Express your answer in kilojoules per mole to four significant figures.
18- The standard enthalpy of formation (ΔH ∘ f) is the enthalpy change that occurs when exactly 1 mol of a compound is formed from its constituent elements under standard conditions. The standard conditions are 1 atm pressure, a temperature of 25 ∘ C and all the species present at a concentration of 1 M.A “standard enthalpies of formation table” containing ΔH ∘ f values might look something like this:
Substance ΔH ∘ f

218 kJ/mol

H 2 (g)
0 kJ/mol

0 kJ/mol

Ba 2+ (aq)
− 538.4 kJ/mol

71 kJ/mol

0 kJ/mol

473 kJ/mol

O 2 (g)
0 kJ/mol

249 kJ/mol

S 2 (g)
129 kJ/mol

Part A
What is the balanced chemical equation for the reaction used to calculate ΔH ∘ f of BaCO 3 (s)? If fractional coefficients are required, enter them as a fraction (i.e., 1/3). Indicate the physical states using the abbreviation (s), (l), or (g) for solid, liquid, or gas, respectively. Use (aq) for aqueous solution.
Express your answer as a chemical equation.
19- For the reaction 2A+B⇌2C+2D, how much heat is absorbed when 3.10mol of A reacts?
Express your answer to three significant figures and include the appropriate units.

20- Ozone, O 3, is destroyed when ClOlevels are high. ClO is likely formed from the decomposition of chlorofluorocarbons (CFCs) in sunlight.
Standard enthalpies of formation for selected substances are given in the table below.
Substance ΔH ∘ f

ClO 2 (g)
O 2 (g)
O 3 (g)
Part A
Calculate the standard enthalpy change of the reaction ClO(g)+O 3 (g)→ClO 2 (g)+O 2 (g) Express your answer in kilojoules using four significant figures.
21- What is the enthalpy for reaction 1 reversed? reaction 1 reversed: N 2 O 4 →N 2 + 2O 2
Express your answer numerically in kilojoules per mole.

22- When 0.501g of biphenyl (C 12 H 10) undergoes combustion in a bomb calorimeter, the temperature rises from 25.2 ∘ C to 29.4 ∘ C. Find ΔE rxn for the combustion of biphenyl in kJ/mol biphenyl. The heat capacity of the bomb calorimeter, determined in a separate experiment, is 5.86 kJ/ ∘ C

23- Instant cold packs, often used to ice athletic injuries on the field, contain ammonium nitrate and water separated by a thin plastic divider. When the divider is broken, the ammonium nitrate dissolves according to the following endothermic reaction: NH 4 NO 3 (s)→NH 4 + (aq)+NO 3 − (aq) In order to measure the enthalpy, change for this reaction, 1.25 g of NH 4 NO 3 is dissolved in enough water to make 25.0 mL of solution. The initial temperature is 25.8 ∘ C and the final temperature (after the solid dissolves) is 21.9 ∘ C. Calculate the change in enthalpy for the reaction. (Use 1.0g/mL as the density of the solution and 4.18J/g⋅ ∘ C as the specific heat capacity.)

24- The change in internal energy for the combustion of 1.0 mol of octane at a pressure of 1.0 atm is 5084.2kJ. If the change in enthalpy is 5074.4kJ , how much work is done during the combustion? answer in kJ


25- It takes 47.0J to raise the temperature of an 11.3g piece of unknown metal from 13.0 ∘ C to 24.1 ∘ C. What is the specific heat for the metal?


26- The molar heat capacity of silver is 25.35 J/mol⋅ ∘ C How much energy would it take to raise the temperature of 11.3g of silver by 19.0 ∘ C? Express your answer with the appropriate units.

27- What is the specific heat of silver?


Quality Assignments Help Website

Cost of your order


Why Choose Us

Top Quality and Well-Researched Papers

We ensure that all your instructions are followed to the letter. You are able to choose the level of interest; professional, college, or high school. We will assign a writer who will cover all your specifications.

Professional and Experienced Academic Writers

We have a team of well trained and experiences assignment writers who are PhD and master’s holders. Our writers are can handle more than 91 disciplines.

Free Unlimited Revisions

If your assignment is not covered to your expectation, you can send your order for revision. The order should be submitted before 10 days elapses for review You can contact our support team or login to your personal account to submit your request.

100% Money-Back-Guarantee

We ensure on-time delivery of your papers. For clarification purpose, we may contact you regarding deadline extension. In case you cannot provide us with more time, we guarantee a 100% refund.

Originality & Confidentiality

We use professional tools to ensure all assignment help documents you receive are free of plagiarism. Our editors ensure optimum review of all quotations in the text. We also ensure confidentiality in our service delivery.

24/7 Customer Support

Our team of experts is available 24/7 to ensure that you are provided with the top customer experience. Any time you need assignment help, you can reach us and get the best experience with ours services.

Our Services

You don’t have to struggle with your papers. You need ample sleep; our writers will cover you. We provide writing services in all disciplines.


Essay Writing Services

No matter what kind of academic paper you need and how urgent you need it, you are welcome to choose your academic level and the type of your paper at an affordable price. We take care of all your paper needs and give a 24/7 customer care support system.


Admission and Business Papers

An admission essay is an essay or other written statement by a candidate, often a potential student enrolling in a college, university, or graduate school. You can be rest assurred that through our service we will write the best admission essay for you.


Editing and Proofreading

Our academic writers and editors make the necessary changes to your paper so that it is polished. We also format your document by correctly quoting the sources and creating reference lists in the formats APA, Harvard, MLA, Chicago / Turabian.


Revision Support

If you think your paper could be improved, you can request a review. In this case, your paper will be checked by the writer or assigned to an editor. You can use this option as many times as you see fit. This is free because we want you to be completely satisfied with the service offered.